无机化学张祖德第二版2版中科大高等教育基础化学教材高中科学竞赛考研辅导书籍 pdf下载

简介：出版社：中国科学技术大学出版社

 

【目录】

总序i

 

前言iii

 

第１部分 化学原理

Part １ Chemical Principles

第1章 气体、液体和溶液的性质3

Chapter 1 The Behaviors of Gas， Liquid and Solution3

1.1 气体的性质3

The Properties of Gases3

1.2 液体17

Liquids17

1.3 溶液23

Solutions23

第2章 化学热力学基础与化学平衡38

Chapter 2 The Basis of Chemical Thermodynamics and Chemical Equilibrium38

2.1 化学热力学的体系与状态38

System and State of Chemical Thermodynamics38

2.2 热力学 定律42

First Law of Thermodynamics42

2.3 热化学47

Thermochemistry47

2.4 热力学第二定律51

Second Law of Thermodynamics51

2.5 化学平衡61

Chemical Equilibrium61

第３章酸碱理论与电离平衡71

Chapter 3 The Theories of Acids & Bases and Ionization Equilibrium71

3.1 酸碱理论71

The Theories of Acids and Bases71

3.2 弱酸弱碱的电离平衡77

The Ionic Equilibrium of Weak Acids and Weak Bases77

3.3 盐的水解89

The Hydrolysis of Salts89

第4章 沉淀反应92

Chapter 4 The Precipitation Reactions92

4.1 溶度积92

Solubility Product92

4.2 沉淀-溶解平衡的移动95

Equilibrium Shift between Precipitation and Dissolution95

4.3 多种沉淀之间的平衡97

Equilibrium in Many Precipitants97

第5章 氧化-还原反应和电化学104

Chapter ５ OxidationReduction Reaction and Electrochemistry104

5.1 氧化-还原反应104

OxidationReduction Reaction104

5.2 电极电势111

Electrode Potential111

5.3 电极电势的应用124

Applications of Electrode Potential124

第６章 化学动力学基础131

Chapter 6 The Basis of Chemical Dynamics131

6.1 化学反应速率131

The Rate of Chemical Reaction131

6.2 化学反应机理154

Reaction Mechanism154

 

第2部分 化学理论

Ｐart ２ Chemical Theories

 

第7章 原子结构和元素周期律163

Chapter 7 The Atomic Structure and Periodic System of Elements163

7.1 原子内部的发现1 

Discovery of Structure in Atom1 

7.2 氢原子光谱和能级的概念170

The Spectrum of Atomic Hydrogen and Concept of Energy Levels170

7.3 原子核外电子的运动状态177

Moving Stations of Electrons outer the Atomic Nucleus177

7.4 多电子原子结构和周期系185

Structure in ManyElectron Atoms and Periodic System185

7.5 元素基本性质的周期性195

Periodic Properties of the Elements195

第8章 化学键和分子、晶体结构202

Chapter 8 Chemical Bonds and Structures of Molecules & Crystals202

8.1 共价键与分子几何构型202

Covalent Bond and Molecular Geometric Structure202

8.2 金属键与金属晶体 232

Metallic Bond and Metallic Crystal232

8.3 离子键与离子晶体243

Ionic Bond and Ionic Crystal243

8.4 晶体学基础257

Basic Crystallology257

第9章 配位化合物267

Chapter 9 The Coordination Compounds267

9.1 配合物的基本概念268

Basic Concepts of Coordination Compounds268

9.2 配位化合物的异构现象279

Isomerism of Coordination Compounds279

9.3 配合物的化学键理论298

The Chemical Bond Theories of Complexes298

9.4 配位平衡及配合物的稳定性315

Coordination Equilibrium and Stabilization of Complex315

9.5 配位化合物的应用322

Application of Coordination Compounds322

第3部分 描述化学

Part3 Descriptive Chemistry



s区和p区元素化学引言331

Introduction of the Chemistry of s and p Elements331

第10章 稀有气体334

Chapter 10 The Rare Gases334

10.1 稀有气体的通性 334

General Properties of Rare Gases334

10.2 氙的化学338

Chemistry of Xenon338



第11章 氢、碱金属和碱土金属345

Chapter 11 Hydrogen， Alkali and Alkaliearth Metals345

11.1氢及其化合物345

Hydrogen and Its Compounds345

11.2 碱金属元素及其化合物351

Alkali Metals and Their Compounds351

11.3 碱土金属及其化合物358

Alkaliearth Metals and Their Compounds358

11.4 专题讨论366

Discussion of Special Subjects366

第12章 卤素369

Chapter 12 The Halogens369

12.1 氟及其化合物370

Fluorine and Its Compounds370

12.2 氯及其化合物374

Chlorine and Its Compounds374

12.3 溴分族380

Bromine Subgroup380

12.4 拟卤素和拟卤化物386

Pseudohalogen and Pseudohalide386

第13章 氧族元素390

Chapter 13 The Oxygen Family Elements390

13.1 氧及其化合物391

Oxygen and Its Compounds391

13.2 硫及其化合物398

Sulfur and Its Compounds398

13.3 硒分族407

The Selenium Subgroup407

第14章 氮族元素412

Chapter 14 The Nitrogen Family Elements412

14.1 氮及其化合物413

Nitrogen and Its Compounds413

14.2 磷及其化合物423

Phosphorus and Its Compounds423

14.3 砷分族431

The Arsenic Subgroup431

第15章 碳族元素436

Chapter 15 The Carbon Family Elements436

15.1 碳及其化合物437

Carbon and Its Compounds437

15.2 硅及其化合物445

Silicon and Its Compounds445

15.3 锗分族450

The Germanium Subgroup450